Yup. Actually cocaine itself is a natural product, it get modified a little depending on how it is extracted from the coca leaves. Now to answer your examine, it is possible to make cocaine from smaller, simpler molecules contained by a lab. Anyone with a sort of advanced acquaintance of organic chemistry can abstractly make (getting a hold of expensive equipment make it hard to do).
I do not know if the "they" you speak of own made some for themselves, but they certinaly could have if they looked-for.
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